{"id":6524,"date":"2020-10-08T07:13:13","date_gmt":"2020-10-08T07:13:13","guid":{"rendered":"http:\/\/www.sci.muni.cz\/ofiz\/?p=6524"},"modified":"2020-10-08T07:13:54","modified_gmt":"2020-10-08T07:13:54","slug":"the-biocompatibility-of-polyaniline-and-polypyrrole-2-doping-with-organic-phosphonates","status":"publish","type":"post","link":"https:\/\/ueb1.sci.muni.cz\/ofiz\/the-biocompatibility-of-polyaniline-and-polypyrrole-2-doping-with-organic-phosphonates\/","title":{"rendered":"The biocompatibility of polyaniline and polypyrrole 2: Doping with organic phosphonates"},"content":{"rendered":"\n<figure class=\"wp-block-image\"><img loading=\"lazy\" decoding=\"async\" width=\"1024\" height=\"625\" src=\"https:\/\/www.sci.muni.cz\/ofiz\/wp-content\/uploads\/2020\/10\/ESC-1024x625.jpg\" alt=\"\" class=\"wp-image-6525\" srcset=\"https:\/\/ueb1.sci.muni.cz\/ofiz\/wp-content\/uploads\/2020\/10\/ESC-1024x625.jpg 1024w, https:\/\/ueb1.sci.muni.cz\/ofiz\/wp-content\/uploads\/2020\/10\/ESC-300x183.jpg 300w, https:\/\/ueb1.sci.muni.cz\/ofiz\/wp-content\/uploads\/2020\/10\/ESC-768x469.jpg 768w, https:\/\/ueb1.sci.muni.cz\/ofiz\/wp-content\/uploads\/2020\/10\/ESC-848x517.jpg 848w, https:\/\/ueb1.sci.muni.cz\/ofiz\/wp-content\/uploads\/2020\/10\/ESC-560x342.jpg 560w, https:\/\/ueb1.sci.muni.cz\/ofiz\/wp-content\/uploads\/2020\/10\/ESC-740x452.jpg 740w, https:\/\/ueb1.sci.muni.cz\/ofiz\/wp-content\/uploads\/2020\/10\/ESC-370x226.jpg 370w, https:\/\/ueb1.sci.muni.cz\/ofiz\/wp-content\/uploads\/2020\/10\/ESC.jpg 1057w\" sizes=\"auto, (max-width: 1024px) 100vw, 1024px\" \/><figcaption><em><strong>The morphology of embryonal stem cells after exposition to the extracts.<\/strong><\/em><\/figcaption><\/figure>\n\n\n\n<p style=\"text-align: justify;\">Conducting polymers (CP) can be used as pH- and\/or electro-responsive components in various bioapplications, for example, in 4D smart scaffolds. The ability of CP to maintain conductivity under physiological conditions is, therefore, their crucial property. Unfortunately, the conductivity of the CP rapidly decreases in physiological environment, as their conducting salts convert to non-conducting bases.<\/p>\n<p style=\"text-align: justify;\">One of the promising solutions how to cope with this shortcoming is the use of alternative &#8220;doping&#8221; process that is not based on the protonation of CP with acids but on interactions relying in acidic hydrogen bonding. Therefore, the phosphonates (dimethyl phosphonate, diethyl phosphonate, dibutyl phosphonate, or diphenyl phosphonate) were used to re-dope two most common representatives of CP, polyaniline (PANI) and polypyrrole (PPy) bases.<\/p>\n<p style=\"text-align: justify;\">As a result, PANI doped with organic phosphonates proved to have significantly better stability of conductivity under different pH. It has also been shown that cytotoxicity of studied materials determined on embryonic stem cells and their embryotoxicity, determined as the impact on cardiomyogenesis and erythropoiesis, depend both on the polymer and phosphonate types used. With the exception of PANI doped with dibutyl phosphonate, all PPy-based phosphonates showed better biocompatibility than the phosphonates based on PANI.<\/p>\n\n\n\n<p style=\"text-align:left\">by<\/p>\n\n\n\n<h5>Zdenka Cap\u00e1kov\u00e1, <strong>Katarzyna Anna Radaszkiewicz<\/strong>, Udit Acharya, Thanh Huong Truong, <strong>Ji\u0159\u00ed Pachern\u00edk<\/strong>, Patrycja Bober, V\u011bra Ka\u0161p\u00e1rkov\u00e1, Jaroslav Stejskal, Ji\u0159\u00ed Pfleger, Mari\u00e1n Lehock\u00fd, Petr Humpol\u00ed\u010dek<\/h5>\n<p style=\"text-align: center;\"><strong><em>In cooperation with Tomas Bata University in Zlin and Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic<\/em><\/strong><\/p>\n\n\n<style>.wp-block-kadence-advancedbtn.kb-btns_57b1d8-50{gap:var(--global-kb-gap-xs, 0.5rem );justify-content:center;align-items:center;}.kt-btns_57b1d8-50 .kt-button{font-weight:normal;font-style:normal;}.kt-btns_57b1d8-50 .kt-btn-wrap-0{margin-right:5px;}.wp-block-kadence-advancedbtn.kt-btns_57b1d8-50 .kt-btn-wrap-0 .kt-button{color:#fff;background:#009900;border-color:#fff;box-shadow:1px 1px 2px 3px rgba(0, 0, 0, 0.2);}.wp-block-kadence-advancedbtn.kt-btns_57b1d8-50 .kt-btn-wrap-0 .kt-button:hover, .wp-block-kadence-advancedbtn.kt-btns_57b1d8-50 .kt-btn-wrap-0 .kt-button:focus{color:#ffffff;border-color:#444444;}.wp-block-kadence-advancedbtn.kt-btns_57b1d8-50 .kt-btn-wrap-0 .kt-button::before{display:none;}.wp-block-kadence-advancedbtn.kt-btns_57b1d8-50 .kt-btn-wrap-0 .kt-button:hover, .wp-block-kadence-advancedbtn.kt-btns_57b1d8-50 .kt-btn-wrap-0 .kt-button:focus{background:#444444;}<\/style>\n<div class=\"wp-block-kadence-advancedbtn kt-btn-align-center kt-btn-tablet-align-inherit kt-btn-mobile-align-inherit kt-btns-wrap kt-btns_57b1d8-50\"><div class=\"kt-btn-wrap kt-btn-wrap-0\"><a class=\"kt-button kt-btn-0-action kt-btn-size-standard kt-btn-style-basic kt-btn-svg-show-always kt-btn-has-text-true kt-btn-has-svg-false\" href=\"https:\/\/www.sciencedirect.com\/science\/article\/pii\/S0928493120301892\"><span class=\"kt-btn-inner-text\">Read the whole story<\/span><\/a><\/div><\/div>\n","protected":false},"excerpt":{"rendered":"<p>Conducting polymers (CP) can be used as pH- and\/or electro-responsive components in various bioapplications, for example, in 4D smart scaffolds. The ability of CP to maintain conductivity under physiological conditions is, therefore, their crucial property. Unfortunately, the conductivity of the &hellip; <a href=\"https:\/\/ueb1.sci.muni.cz\/ofiz\/the-biocompatibility-of-polyaniline-and-polypyrrole-2-doping-with-organic-phosphonates\/\">Read More<\/a><\/p>\n","protected":false},"author":5,"featured_media":6525,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"kt_blocks_editor_width":"","_exactmetrics_skip_tracking":false,"_exactmetrics_sitenote_active":false,"_exactmetrics_sitenote_note":"","_exactmetrics_sitenote_category":0,"footnotes":""},"categories":[252],"tags":[],"class_list":["post-6524","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-nova-publikace"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v26.1.1 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>The biocompatibility of polyaniline and polypyrrole 2: Doping with organic phosphonates - Department of Animal Physiology and Immunology<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/ueb1.sci.muni.cz\/ofiz\/the-biocompatibility-of-polyaniline-and-polypyrrole-2-doping-with-organic-phosphonates\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"The biocompatibility of polyaniline and polypyrrole 2: Doping with organic phosphonates - Department of Animal Physiology and Immunology\" \/>\n<meta property=\"og:description\" content=\"Conducting polymers (CP) can be used as pH- and\/or electro-responsive components in various bioapplications, for example, in 4D smart scaffolds. The ability of CP to maintain conductivity under physiological conditions is, therefore, their crucial property. 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The ability of CP to maintain conductivity under physiological conditions is, therefore, their crucial property. 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